Mass-production of biomimetic fur knitted triboelectric fabric for smart home and healthcare

Advanced Materials

Triboelectric nanogenerators offer an environmentally friendly approach to harvesting energy from mechanical excitations. This capability has made them widely sought‐after as an efficient, renewable, and sustainable energy source, with the potential to decrease reliance on traditional fossil fuels. However, developing triboelectric nanogenerators with specific output remains a challenge mainly due to the uncertainties associated with their complex designs for real‐life applications. Artificial intelligence‐enabled inverse design is a powerful tool to realize performance‐oriented triboelectric nanogenerators. This is an emerging scientific direction that can address the concerns about the design and optimization of triboelectric nanogenerators leading to a next generation nanogenerator systems. This perspective paper aims at reviewing the principal analysis of triboelectricity, summarizing the current challenges of …

The growing popularity of the Internet of Things has led to increases in the need for renewable energy and sensor systems. Therefore, triboelectric nanogenerators (TENGs) have garnered significant attention as a novel form of energy production due to their lightweight nature, cost-effectiveness, high output, and versatility in terms of materials, low cost, and device configurations. TENGs have been studied for several uses, including self-powered sensing, biomedical, biomotion, healthcare monitoring, and robotic applications. The performance of TENG is drastically pretentious by the material because charge density (σ) is an inherent characteristic of the material. Metal-organic framework (MOF) materials possess robust charge-trapping capabilities, multifunctional structures, adjustable properties, and exceptional stability. These materials can be utilized or integrated as self-powered sensors of different kinds to …

Advanced Materials Technologies

Although natural evaporation absorbs substantial thermal energy from the ambient environment, efficiently utilizing this high‐entropy energy remains challenging. Here, the first water evaporation‐induced triboelectric nanogenerator is proposed. It only uses tap water to harvest low‐grade heat energy from the surroundings to convert it into electricity. The natural evaporation of the liquid can generate unintermittent electricity with an open‐circuit voltage of 382 V, a peak power of 0.42 mW, and three orders of magnitude enhancement up to 59.7 mJ mL−1 after consuming the same amount of tap water compared with the droplet‐based electricity generators. After which, the excellent power output lights 2 W LED and drives wearable electronic devices. This device also inhibits carbon steel materials' corrosion in solutions through the evaporation effect of the salt water on the spot. The present study provides novel …

Nano Energy

Tactile perception systems as the medium between the ambient environment and robotics lie in the heart of modern artificial intelligence. By providing different electronic readouts under various circumstances, they can give easily captured information for post-processing. However, for applications of most reported tactile perception systems, external location assistances are still needed. Here, as inspired by the platypus’ sixth sense, we developed a new kind of tactile perception system based on triboelectric sensors with the additional function from quantum rods. This terminal can be used as a single-electrode mode triboelectric nanogenerator for both location detection and vertical force sensing with high sensitivity and fast response. Moreover, by adding CdSe/CdS quantum rods into an imprinted polydimethylsiloxane film, different lateral stretching levels can be perceived by a modified luminescence. Supported …

Energy & Environmental Science

Controlling the motion of charge carriers in semiconductor materials is a fundamental strategy for achieving many functional devices, which is typically achieved by applying an external voltage source. Herein, using the electrostatic potential generated by a triboelectric material taken as a sliding “gate”, a functional current is generated across a semiconductor channel when the gate is moving in parallel to the dielectric surface. Systematic studies verify that the motion of the electrified “gate” induces the regional and dynamical doping of the semiconductor channel, thereby driving the carrier transport without applying an external voltage. This sliding-gated generator achieves mechanoelectric energy conversion based on the coupled triboelectrification effect and electrostatic field effect and is therefore termed as a field effect nanogenerator (FENG). It can output electrical currents with a waveform that follows well with …

Advanced Materials Technologies

Wearable and implantable triboelectric nanogenerators (TENGs) convert mechanical energy to electricity in the daily movements of the human body. Self‐generated dynamic electric field or displacement current of TENGs can operate from micrometers to centimeters, which offers a key technology for TENG‐based therapy systems for precision medicine on both tissues and cells. TENGs have low‐current and high‐voltage properties, which reduce damage to normal tissues, and kill rapidly dividing cancer cells. In this work, the dynamic electric field from TENG directly inhibits the cellular proliferation behavior of cancer cells. The work paves a new way for the self‐generated electric field of TENG for cancer therapy.

Journal of Power Sources

High-frequency supercapacitors (HF–SCs) are promising electric energy storage devices and alternating current line filters. However, severe self-discharge of HF–SCs causes significant energy loss and limits their applications. Current self-discharge suppression methods for supercapacitors typically lead to decreased rate performance and hence cannot be applied to HF–SCs directly. In this work, barium titanate (BTO) nanoparticles are employed as an electrolyte additive for HF–SCs to reduce self-discharge. By adding BTO nanoparticles into the electrolyte, both leakage current and decay of open circuit voltage of the devices are reduced without sacrificing the specific capacitance and high-frequency response. At a charging voltage of 2 V, the leakage current is reduced by 49 % (3.91 vs. 1.98 μA), while the time for the voltage to drop from 2.0 to 1.0 V is extended by 4.5 times (2300 vs. 10240 sec). When the HF …

Small

Shelter forests (or shelter‐belts), while crucial for climate regulation, lack monitoring systems, e.g., Internet of Things (IoT) devices, but their abundant wind energy can potentially power these devices using the trees as mounting points. To harness wind energy, an omnidirectional fluid‐induced vibration triboelectric nanogenerator (OFIV‐TENG) has been developed. The device is installed on shelter forest trees to harvest wind energy from all directions, employing a fluid‐induced vibration (FIV) mechanism (fluid‐responding structure) that can capture and use wind energy, ranging from low wind speeds (vortex vibration) to high wind speeds (galloping). The rolling‐bead triboelectric nanogenerator (TENG) can efficiently harvest energy while minimizing wear and tear. Additionally, the usage of double electrodes results in an effective surface charge density of 21.4 µC m−2, which is the highest among all reported …

Advanced Materials

Recently, perovskite photodetectors (PDs) have been risen to prominence due to substantial research interest. Beyond merely tweaking the composition of materials, a cutting‐edge advancement lies in leveraging the innate piezoelectric polarization properties of perovskites themselves. Here, the investigation shows utilizing Ti3C2Tx, a typical MXene, as an intermediate layer for significantly boosting the piezoelectric property of MAPbI3 thin films. This improvement is primarily attributed to the enhanced polarization of the methylammonium (MA+) groups within MAPbI3, induced by the OH groups present in Ti3C2Tx. A flexible PD based on the MAPbI3/MXene heterostructure was then fabricated. The new device is sensitive to a wide range of wavelengths, displays greatly enhanced performances owing to the piezo‐phototronic coupling. Moreover, the device is endowed with a greatly reduced response time, down …

Energy & Environmental Science

Establishing maintenance-free wireless sensor networks for online monitoring of power transmission lines is crucial for realizing smart grids, exhibiting necessitating energy harvesters with compact volume, excellent robustness, and efficient, well-regulated output. This study introduces a hybrid magnetic energy harvester (HMEH), seamlessly integrating a magneto-mechanical energy conversion module, a non-contact rotational triboelectric nanogenerator (TENG) module, and an electro-magnetic generator (EMG) module for magnetic energy harvesting and self-powered sensing in power transmission lines. The HMEH converts magnetic energy into synchronized mechanical rotation using the magnetic phase difference principle and smoothly transforms it into a regulated electrical energy output. With a compact size of 5 cm × 5 cm × 3 cm and a light weight of 56 g, the HMEH showcases unprecedented volume and …

ACS Applied Materials & Interfaces

The global annual vegetable and fruit waste accounts for more than one-fifth of food waste, mainly due to deterioration. In addition, agricultural product spoilage can produce foodborne illnesses and threaten public health. Eco-friendly preservation technologies for extending the shelf life of agricultural products are of great significance to socio-economic development. Here, we report a dual-functional TENG (DF-TENG) that can simultaneously prolong the storage period of vegetables and realize wireless storage condition monitoring by harvesting the rotational energy. Under the illumination of the self-powered high-voltage electric field, the deterioration of vegetables can be effectively slowed down. It can not only decrease the respiration rate and weight loss of pakchoi but also increase the chlorophyll levels (∼33.1%) and superoxide dismutase activity (∼11.1%) after preservation for 4 days. Meanwhile, by …

Nature Communications

Harvesting biomechanical energy from cardiac motion is an attractive power source for implantable bioelectronic devices. Here, we report a battery-free, transcatheter, self-powered intracardiac pacemaker based on the coupled effect of triboelectrification and electrostatic induction for the treatment of arrhythmia in large animal models. We show that the capsule-shaped device (1.75 g, 1.52 cc) can be integrated with a delivery catheter for implanting in the right ventricle of a swine through the intravenous route, which effectively converts cardiac motion energy to electricity and maintains endocardial pacing function during the three-week follow-up period. We measure in vivo open circuit voltage and short circuit current of the self-powered intracardiac pacemaker of about 6.0 V and 0.2 μA, respectively. This approach exhibits up-to-date progress in self-powered medical devices and it may overcome the inherent …

Advanced Materials

Although dielectric elastomer actuators (DEAs) are promising artificial muscles for use as visual prostheses in patients with oculomotor nerve palsy (ONP), high driving voltage coupled with vulnerable compliant electrodes limits their safe long‐term service. Herein, a self‐healable polydimethylsiloxane compliant electrode based on reversible imine bonds and hydrogen bonds is prepared and coated on an acrylic ester film to develop a self‐healable DEA (SDEA), followed by actuation with a high‐output triboelectric nanogenerator (TENG) to construct a self‐powered DEA (TENG‐SDEA). Under 135.9 kV mm−1, the SDEA exhibits an elevated actuated strain of 50.6%, comparable to the actuation under DC power. Moreover, the mechanically damaged TENG‐SDEA displays a self‐healing efficiency of over 90% for 10 cycles. The TENG ensures the safe using of TENG‐SDEAs and an extraocular‐muscle‐like actuator …

Chemical Engineering Journal

Triboelectric nanogenerators (TENGs) and lithium-ion batteries (LIBs) play an important role in the field of clean energy as energy conversion and storage devices respectively. It is vital to fabricate efficient transport between TENGs and LIBs for promoting the development in combined energy systems. This work constructs an efficient energy transport system between the contact-energy contact-separation TENG (CCS-TENG) and the LIB by introducing power management based on a short-circuit contact in-situ. Such synergy system satisfies the needs of improving the efficient connection between TENGs and LIBs, durability and miniaturization of energy unit. The short-circuit contact in-situ guarantees the maximum energy output of CSS-TENG in every contact-separation cycle and the energy density is as high as 131.1 mJ m−2 cycle−1, although the electrode of CCS-TENG is only 10 cm2. Moreover, the TENG cycle …

Advanced Functional Materials

The utilization of unmanned aerial vehicles (UAVs) is on the rise across various industries. In such a scenario, the issue of flight safety for these UAVs becomes increasingly paramount. Currently, UAVs exhibit shortcomings in flight attitude perception compared to more mature manned aircraft, especially concerning the position sensing of flight actuation, which poses significant safety risks. Mature position monitoring solutions for flight actuation used in manned aircraft cannot be directly integrated into systems of UAV due to compatibility issues. This necessitates the development of new position sensing technologies to address this challenge. Triboelectric nanogenerators, with their advantages of miniaturization, self‐powering capabilities, and the ability to generate voltage‐level electrical signals, are chosen to form a part of the position detection system for sensors in UAVs. In this study, a self‐powered …

As one of the few self-powered instruments and devices, triboelectric nanogenerators (TENGs) have been developed for more than 10 years since its invention in 2012. With wide material selections and diverse design structures, and without having to use an external power supply, TENG has been applied in many key technologies. By the end of 2022, more than 16,000 researchers from 83 countries and regions around the world have authored scientific papers in TENG. In this review, we start from the theoretical principles and working mechanisms of TENG, and discuss its 5 major fields of application, namely, as self-powered sensors, high-voltage energy devices, blue energy devices, micro/nano-energy devices, and solid–liquid interface probes. Next, we review the breakthrough progress made using TENG as commercial products in the following fields: medical health, intelligent security, and marine energy …

Nano Energy

While triboelectric nanogenerated knitted fabrics are regarded as a state-of-the-art and reliable energy source for wearable electronics, there are two bottlenecks in their widespread applications: few mass-manufacturing strategies and low power output. Here, by mature weft-knitted technologies, a 3D single-faced jacquard pile fabric TENG (SJPF-TENG) with the merits of high surface pile density, excellent comfort and breathability, good thermal insulation property, and superior durability, is mass-produced. Based on the high-density pile structure (about 16128 piles per cm2), the surface area of pile fabrics is 42.2 times that of the plain structure, which endows the SJPF-TENG with higher electrical outputs and good detection precision. With a peak power density of 1.4 W m−2 (dozens of times that of conventional textile-based TENGs), the SJPF-TENG is capable of lighting up 1392 light-emitting diodes, powering …

IEEE Sensors Journal

Accurate rainfall monitoring carries significant importance across meteorological and hydrological domains. However, existing sensors face numerous challenges, including issues related to accuracy, stability, and limited measurement range, particularly during heavy rain events. Here, an innovative droplet-based triboelectric nanogenerator (D-TENG) rain gauge is proposed to overcome the above challenges. It incorporates a saddle-shaped rainfall bearing plate designed to channel rainwater for regular dripping onto the D-TENG, thereby generating electrical signals for droplet enumeration. The feasibility of the D-TENG rain gauge is substantiated through the analyses of the stability of the electrical signal (short-circuit current) and droplet weight. Experimental results illustrate the effective measurement range of the D-TENG rain gauge as 0-243.1 mm/h, with the relative error in calculated rainfall intensity within ±4 …

Nano Energy

Multi-direction, irregularity, low-grade, the dynamic characteristics of low-grade airflow energy are prominent that making it difficult to collect. Here, we propose a vibration-coupled triboelectric nanogenerator (VC-TENG) induced by vortex to achieve from weak to ultra-strong vibration, thus effectively converting low-grade airflow energy into vibrational mechanical energy, and then electric energy. The transferred charge and short-circuit current increases is 47 and 26.9 times due to designed vortex structure, and the resonant response time is 2 s at a speed of 4.1 m/s. A VC-TENG unit delivers a peak power of 4.5 mW under a load resistance of 500 MΩ. A grouping of applied demonstrations of self-powered system validates the practicality and durability of VC-TENG. This work offers a practical strategy for harvesting low-grade airflow energy, and is a promising distributed power technologies for self-powered monitoring …

Nano Energy

The fragmentation caused by cracks spreading along grain boundaries seriously deteriorates the cycling performance of high nickel (Ni ≥ 90%) layered cathode materials for lithium-ion batteries (LIBs). In this study, heterogeneous nucleation was utilized to epitaxially grow LiNbO3 layer onto LiNi0.90Co0.05Mn0.05O2 (NCM90). Importantly, the LiNbO3 layer was compatible with the highly reactive surface of NCM90. The formation process of LiNbO3 solid embryos was calculated and discussed based on crystal solidification theory, and the distribution of solid embryos revealed thin zone crystallization and aggregation zone grain pinning. More interestingly, the surface stiffness and surface Young's modulus of the NCM90 were significantly enhanced, and the grain movement (fragmentation) caused by the non-uniform contraction of the unit cell was bound correspondingly at high cut-off voltages. Originating from the …

Nano Energy

We introduce a manufacturing concept of variable capacity energy harvesters consisting of macroporous springs integrated within a conducting silicone rubber and dielectric. Printing and polymerising emulsion templates resulted in macroporous spring elements, which were coated with conducting silicone rubber to maintain the active contact surface. By increasing size and number of these springs, the capacitance change of the energy harvesters during compression and recovery increased from 0.4 nF/cm2 to 0.8 nF/cm2. During cyclic loading with 30 N at 2 Hz, the energy harvesters with macroporous springs delivered a power density of 0.58 µW/cm2 at a bias voltage of 50 V, which was 25 times higher than the control without springs. The energy harvesters provided a constant power output over three hours of cyclic loading (21,600 cycles), indicating their structural stability and the durability of the …

Nano Energy

Quasi-two-dimensional (quasi-2D) perovskite materials have attracted significant attention for application in light-emitting diodes (PeLEDs) due to their unique optical characteristics and extraordinary performance. The inherent multi-quantum well structure will generate a strong quantum confinement effect which is beneficial for the blue emission. However, the efficiency and stability of the quasi-2D blue PeLEDs lag behind their red and green counterparts, which prevents the further commercial application of the PeLEDs. The performance of quasi-2D blue PeLEDs was limited on account of the inefficient phase distribution management, which causes an inefficient energy transfer and severe non-radiative recombination. Herein, we employ guanidine thiocyanate (GASCN) as the pre-deposited film at the bottom of the perovskite film to manage the phase distribution of the PBA2Csn−1PbnBr3n+1 quasi-2D perovskite …

Nano Energy

Current thermochromic smart windows based on lower critical solution temperature (LCST) behavior can achieve solar regulation and energy saving by modulating solar transmission at the cost of visibility at higher temperature. To tackle this issue, a new concept of smart window based on the upper critical solution temperature (UCST) characteristic of zwitterionic hydrogel has been developed, giving daytime luminous transparency, all day radiative cooling and nighttime privacy protection. This design rule is suitable for energy saving smart windows for regions where cooling demand is dominant. The UCST smart window panel provides moderate luminous transmission (Tlum) of 37.1% and low near-infrared transmission (TNIR) of 20.3% during the daytime, all day near unity long-wave infrared emissivity (ƐLWIR) of 0.96 facing outdoor to promote radiative cooling with outer space, low ƐLWIR 0.19 facing indoor to …

Nano Energy

LiNi0.5Mn1.5O4 (LNMO) spinel cathode is a potential cathode material for high-power, low-cost lithium-ion batteries (LIBs) due to its low raw material cost, high operating voltage and efficient lithium-ion transport channel. However, LNMO suffers from structural stability due to the two-phase-transformation during charge/discharge process, leading to poor cycling performance. To address the issues, we have constructed a homogeneous aggregated LNMO cathode with a multifaceted primary particle, namely the LNMO with single-crystal secondary particles (SSP LNMO). Ex situ and in situ characterizations including the synchrotron X-ray diffraction, the neutron diffraction and full pouch cell validated that the SSP LNMO exhibit a single solid-solution reactions with a restrained lattice evolution during the delithiation/ lithiation process. This is in contrast to the normal LNMO cathode, which demonstrates a significant two …

Nano Energy

Parkinson’s disease (PD) is a neurodegenerative disease with dopaminergic neurons loss, which induces dopamine reduction and body motion disorder. Traditional deep brain stimulation (DBS), which involves the implanting metal electrodes into the subcortical nucleus of the brain, has a huge risk of invasive surgery and low resolution. Here we present that pomegranate-like piezoelectric nanogenerators are able to efficiently transduce ultrasonic wave into electric power generation under ultrasound stimulation, which modulates intracellular calcium signaling and tyrosine hydroxylase levels to activate the neuron activity and process of deep-brain tissue in vitro and in vivo. Strikingly, after one-week nanogenerator-mediated neuromodulation, the damaged dopaminergic neurons in PD-zebrafish and mice were reversed with a decrease in α-synuclein aggregates and an increase in tyrosine hydroxylase for …

Nano Energy

This study introduces a general label-free drug screening platform with potential to support high-throughput drug screening for any protein target. Its innovation lies in quantifying the affinity of molecule-molecule interactions via voltage output variation, which achieves unprecedented selectivity and sensitivity. It combines computational analysis complemented by experimental substantiation with a solid-liquid triboelectric nanosensor. Owing to its high binding affinity, FKBP-rapamycin is used as a model system to demonstrate the platform's sensitivity. Subsequently, the research is extended to study drug interactions with an oncogenic protein ATG4B. The findings unveil the binding of S130 and Tioconazole to ATG4B, a critical cysteine protease involved in autophagy, while revealing that Dexamethasone does not bind ATG4B. This binding exerts a specific inhibitory effect on autophagic flux and triggers cancer cell …

Nano Energy

In the context of livestock farming, controlling dust within barns is vital for maintaining animal respiratory health, equipment longevity, and production efficiency. To address the challenges posed by high dust concentrations, ventilation systems with air filters and humidity controls have been introduced. However, their widespread adoption on family farms is hindered by their high costs, substantial energy consumption, and labor-intensive maintenance. To address this pressing issue, we propose a self-powered air purification system (SAPS) based on a wind-driven soft-contact triboelectric nanogenerator (SC-TENG), specifically tailored for deployment within livestock barns. Leveraging the low wear and strong charge-donating properties of rabbit hair as the triboelectric material, the SC-TENG efficiently harnesses low-speed wind energy near the ground, consistently generating a high voltage of ∼3000 V …

Nano Energy

During the past decade, Triboelectric Nanogenerators (TENG) have demonstrated their potential as an energy harvesting and self-powered sensing technology for future wearable applications. Among various TENG architectures, knitted textile TENGs have become increasingly popular in recent times, as they provide advantages such as high electrical outputs, very good mechanical properties and excellent wearability. However, there is still a lack of understanding on how to engineer the knitting parameters to maximize the electrical output generation of knitted textile TENGs. Herein, for the first time, we bridge this gap by mapping the relationship between basic knit parameters and the fundamental TENG parameters which govern their electrical outputs. In this work, the loop length, yarn count, number of yarns per loop and the loop structure of a knitted textile TENG are empirically varied and its impact on the …

Nano Energy

The electrochemical reduction of CO2 is an effective approach to reduce and utilize CO2 for carbon neutral under mild conditions, meanwhile, the development of efficient and stable catalysts with large area and low cost is more conducive to the industrialization of CO2 electroreduction. The metal-oxide heterogeneous interface can promote the activation and conversion of CO2 due to the synergy effect between the metal and the oxide. Therefore, Cu/In2O3 electrodes are fabricated by magnetron sputtering in one step to achieve high selectivity of CO or CH3OH at different potentials. The highest Faradaic efficiency of CO is 78% at − 0.75 V, and unexpectedly, the Faradaic efficiency of CH3OH at − 0.55 V can reach 56%. The abundance of heterogeneous interfaces in Cu/In2O3 provides more active sites, reduces the work function and shifts the d‐band center upward. The catalytic performance was improved by …

Nano Energy

With the rapid advancement of the Internet of Things, a wide range of information interaction platforms have been developed to enhance the quality of life and work. Nevertheless, rigid batteries greatly limit its development, which requires frequent replacement or recharge. Thermoelectric generators (TEG) have emerged as an attractive form for energy suppliers owing to their ability to convert low-grade energy heat into sustainable electricity. Herein, we have implemented a flexible TEG-based multifunctional information interaction system, which utilizes body heat to enable information interaction through finger touch. To increase the efficiency of energy conversion, the flexible TEG achieves high performance by optimizing the filling factor and material thermal conductivity, leading to a normalized power density of 1.43 μW/cm2 K2. As a proof-of-concept demonstration, the system has been applied to food spoilage …

Nano Energy

Artificial intelligence of things (AIoT) aims to establish smart informative interactions between humans and devices. However, common pixelated sensing arrays in AIoT applications present problems, such as hard and brittle devices, intricate wiring, complex structures, signal transmission crosstalk, and low precision. Herein, we show an innovative solution called all-in-one intelligent semitransparent interactive nerve patch (AISI nerve patch), which is realized by an electrical double-layer parallel separation structure with homogeneous soft conductive materials. Multifunctionality of sensing, recognition, and transmission is integrated into the AISI nerve patch, while its total thickness can be limited to the microscale level. The AISI nerve patch possesses favorable semitransparency (transmittance of ∼80%), which enables the interactive area not only to be accurately identified but also not to affect aesthetics. High …

Nano Energy

Extreme frictional wear of triboelectric layers severely hinders long-term sustainability of triboelectric nanogenerators (TENGs) for efficient ambient energy harvesting. The state-of-the-art solutions necessitate sophisticated structural designs and complex packaging constraints, impeding the feasibility of TENGs for practical applications. Herein, inspired by the structures and compositions of snake scales, a biomimetic composite (BC) film is fabricated as a wear-resistant triboelectric contact layer. The successful formation of disulfide bond-facilitated cross-linkage of cysteine proteins in the keratin-based BC film promotes excellent mechanical resilience and durability, thereby solving the material abrasion challenges associated with solid-solid triboelectric layers. The BC film, with toothed microstructure, exhibits improved charge transfer, low friction, and consistent long-term stable outputs compared to commercial films …

Nano Energy

The inherent dynamic behavior observed in 2D‐3D interfaces in perovskite solar cells (PSC), driven by ion diffusion and migration, poses a significant challenge in establishing a stable passivation and barrier interface that can fulfill the device's complete lifecycle requirements. In this work, we construct large sterically hindered one-dimensional (1D) perovskite crystals integrated with the perovskite surface and observed their evolution during accelerated aging for the first time. The results show that this strong interfacial bonding not only effectively passivates surface defects but also prevents interface reconstruction due to migration, even under elevated temperatures. Moreover, it serving as an effective barrier can significantly suppress the interdiffusion between the copper electrode and the perovskite layer. Resultantly, our approach attained a remarkable efficiency of 23.3% via a scalable coating process in FA0.3 …

Nano Energy

Due to the large volume expansion, the multiple issue of severe pulverized Si particles, irreversible damaged electrode structure, and incompatible solid electrolyte interphase (SEI), have greatly restricted the practical application of Si-based anodes. Herein, a neutral partially lithiated binder (PVA1-g-LiPAA3) is successfully synthesized and applied in high-loaded SiOx||Li, 200 mA h and 4 A h SiOx/graphite||LiCoO2 pouch cells. The rich netural -OH and -COOLi groups show strong interaction with the Si particles during long-term cycling processes. Neutral PVA1-g-LiPAA3 binder can induce the formation of a homogenous and stable “core-shell” SEI film on the SiOx anodes, forbidding the structural evolution and volume expansion. This -CF3-rich SEI film can also improve the ionic conductivity and accelerate the electrochemical kinetics reaction. Moreover, the integrity of fluid collection and polar ears can also be …

Nano Energy

The morphology regulation of active layer has an important role in the development of organic solar cells (OSCs), which can improve device performance and prolong device stability. Herein, we propose the commonly used donors building block, benzo[1,2-b:4,5-b']dithiophene (BDT), as a novel volatile solid additive into PM6:Y-series solar cells. BDT can be well mixed with accepter Y6 by molecular interaction. Therefore, compared with the control film, the BDT-processed film achieves improved aggregation and enhanced crystallinity. Owing to the synergetic effects on the phase separation and molecular arrangement, the device processed with BDT exhibits the significantly enhanced exciton dissociation, charge transfer and collection along with the suppressed bimolecular recombination. Consequently, the device based on PM6:Y6 with BDT-processing obtains the 17.91% power conversion efficiency (PCE) and …

Nano Energy

Strain engineering involves intentionally inducing lattice distortion in materials to manipulate their electronic and geometric properties, along with the accompanying bond strength between reactants and catalysts. This approach presents an appealing pathway to optimize catalytic performance. However, it confronts challenges in achieving precise control, scalability and controllable modulation of intermediate species’ adsorption and desorption. Herein, we report a dynamic strain engineering method achieved through ultrasonic cavitation-induced high and low-pressure cycles, enabling periodically adjustable adsorption/desorption properties while bypassing complex synthesis procedures. Illustrated using ZnO and CO2 piezo-reduction reaction as a demonstration, theoretical studies initially predict that adsorption of intermediates *COOH can be regulated within a specific range of strains. Under ultrasonic …

Nano Energy

The hybrid 2D/3D heterostructure, which synergistically combine the high surface area and superior surface properties of 2D materials with the volumetric advantages and mechanical stability of 3D materials, offer an efficient and unique platform for electronic, optoelectronic, and energy conversion applications. Although this structure offers numerous advantages, optimizing the performance of 2D/3D heterojunction devices still faces challenges such as interface control difficulty, doping uniformity, and scalability for mass production. To simplify and effectively optimize the performance of 2D/3D heterojunction devices, this study delves into the impact of the thickness of 2D Bi 2 Se 3 films on the performance of Bi 2 Se 3/GaN heterojunction photodetectors. In thinner Bi 2 Se 3 films, a higher surface defect density increases carrier recombination efficiency, while in thicker films, an increase in internal defects impedes …

Nano Energy

In an era marked by a growing demand for sustainable energy solutions and resilient disaster management systems, the convergence of innovative technologies holds the promise of addressing multifaceted challenges. This manuscript explores the multifunctional capabilities of the "smart maracas", a novel triboelectric nanogenerator (TENG) designed to harvest mechanical energy and simultaneously serve as an earthquake sensor. The smart maracas is a striking example of the potential of TENGs to harness mechanical motion for practical applications. The device converts mechanical energy into electrical power through meticulous engineering, opening avenues for self-sustaining power sources in various domains. The manuscript outlines the device's structural design, working principle, and real-time applications, spanning bio-mechanical energy harvesting, vibrational energy scavenging, rotational energy …

Nano Energy

Versatile and recyclable conductive hydrogels with long-term environmental adaptability and mechanical stability have attracted tremendous attention in wearable smart electronics. Here, double-network (DN) polyvinyl alcohol (PVA)/cellulose hydrogels were constructed after introducing a conductive rigid cellulose/Zn2+/Ca2+ network into a soft PVA/borax network. The resultant hydrogels possessed good mechanical and self-adhesive properties, along with transparency, recyclability, and remarkable resistance to freezing. They showed 30-day non-drying properties due to the presence of hygroscopic salts through a dynamic moisture adsorption and desorption process. Dehydrated hydrogels can return to their original states via self-regeneration under high relative humidity. Hydrogel-based strain sensors retained good sensitivity and a wide sensing range during the wide working temperature ranging from -40 °C …